diff --git a/examples/Data/DoubleLayerCapacity/PB.npz b/examples/Data/DoubleLayerCapacity/PB.npz
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diff --git a/examples/ReproducableCode/DoubleLayerCapacity/PB.py b/examples/ReproducableCode/DoubleLayerCapacity/PB.py
new file mode 100644
index 0000000000000000000000000000000000000000..d9a8263bcd365d4d77b27feef1bfb1846b51678b
--- /dev/null
+++ b/examples/ReproducableCode/DoubleLayerCapacity/PB.py
@@ -0,0 +1,113 @@
+'''
+Jan Habscheid
+Jan.Habscheid@rwth-aachen.de
+
+This script is used to analyze the influence of the molarity on the charge of the system and the double-layer capacity.
+'''
+
+# import the src file needed to solve the system of equations
+import sys
+import os
+
+# Add the src directory to the sys.path
+src_path = os.path.join(os.path.dirname(os.path.abspath(__file__)), '../../..', 'src')
+sys.path.insert(0, src_path)
+
+from Eq04 import solve_System_4eq
+from Helper_DoubleLayerCapacity import Phi_pot_center, C_dl, n, Q_num_, Q_num_dim
+from Eq04 import solve_System_4eq
+
+# Remove the src directory from sys.path after import
+del sys.path[0]
+
+# Import plotting library
+import matplotlib.pyplot as plt
+import numpy as np
+
+# Define Parameter
+e0 = 1.602e-19 # [As]
+k = 1.381e-23 # [J/K]
+T = 293.75 # [K]
+epsilon0 = 8.85e-12 #[F/m]
+F = 9.65e+4 # [As/mol]
+NA = 6.022e+23 # [1/mol] - Avogadro constant
+nR_mol = 55
+nR_m = nR_mol * NA * 1/(1e-3)# [1/m^3]
+pR = 1.01325 * 1e+5 # [Pa]
+LR = 20e-9
+chi = 80 # [-]
+
+# Parameter and bcs for the electrolyte
+Lambda2 = (k*T*epsilon0*(1+chi))/(e0**2 * nR_m * (LR)**2)
+a2 = (pR)/(nR_m * k * T)
+K = 'incompressible'
+Molarity = 0.01
+y_R = Molarity / nR_mol
+z_A, z_C = -1.0, 1.0
+phi_R = 0.0
+p_R = 0
+
+# Solver settings
+number_cells = 1024
+relax_param = 0.3
+rtol = 1e-2 # ! 1e-8
+refinement_style = 'hard_log'
+max_iter = 10_000
+return_type = 'Vector'
+
+# phi^L domain
+Volt_start = -0.35
+Volt_end = 0.35
+n_Volts = 25 # ! 75
+
+Phi_Pot_Diff_dim_PB = np.linspace(Volt_start, Volt_end, n_Volts)
+Phi_Pot_Diff_dimless_PB = Phi_Pot_Diff_dim_PB * e0/(k*T)
+
+phi_PB, y_A_PB, y_C_PB, y_S_PB, p_PB,x_PB = [], [], [], [], [], []
+for i, phi_bcs in enumerate(Phi_Pot_Diff_dimless_PB):
+ y_A_, y_C_, phi_, p_, x_ = solve_System_4eq(phi_bcs, phi_R, p_R, z_A, z_C, y_R, y_R, K, Lambda2, a2, number_cells, solvation=0, PoissonBoltzmann=True, refinement_style='hard_log', rtol=rtol, max_iter=max_iter, relax_param=0.01, return_type=return_type)
+ y_A_PB.append(y_A_)
+ y_C_PB.append(y_C_)
+ y_S_PB.append(1 - y_A_ - y_C_)
+ phi_PB.append(phi_)
+ p_PB.append(p_)
+ x_PB.append(x_)
+
+
+# Charge
+Q_DL_dimless_PB_ = []
+Q_DL_dim_PB_ = []
+for j in range(len(Phi_Pot_Diff_dimless_PB)):
+ Q_DL_dimless_PB_.append(Q_num_(y_A_PB[j], y_C_PB[j], n(p_PB[j], K), x_PB[j], z_A, z_C))
+ Q_DL_dim_PB_.append(Q_num_dim(y_A_PB[j], y_C_PB[j], n(p_PB[j], K), x_PB[j], z_A, z_C, nR_m, e0, LR))
+Q_DL_dimless_PB_ = np.array(Q_DL_dimless_PB_)
+Q_DL_dim_PB_ = np.array(Q_DL_dim_PB_)
+
+# Double-layer capacity
+C_DL_dimless_PB = C_dl(Q_DL_dimless_PB_, Phi_Pot_Diff_dimless_PB)
+C_DL_dim_PB = C_dl(Q_DL_dim_PB_, Phi_Pot_Diff_dim_PB)
+
+Phi_pot_center_array_dimless_PB = Phi_pot_center(Phi_Pot_Diff_dimless_PB)
+Phi_pot_center_array_dim_PB = Phi_pot_center(Phi_Pot_Diff_dim_PB)
+
+# Plotting
+# Charge
+fig, axs = plt.subplots()
+axs.plot(Phi_Pot_Diff_dim_PB, Q_DL_dim_PB_)
+axs.grid()
+axs.set_xlabel('$\delta \\varphi [nm]$')
+axs.set_ylabel('$Q$ [\u03bc$F/cm^3]$')
+fig.tight_layout()
+fig.show()
+
+# Double-layer capacity
+fig, axs = plt.subplots()
+axs.plot(Phi_pot_center_array_dimless_PB, C_DL_dimless_PB)
+axs.grid()
+axs.set_xlabel('$\delta \\varphi [-]$')
+axs.set_ylabel('$Q [-]$')
+fig.tight_layout()
+fig.show()
+
+# Store results
+np.savez('../../Data/DoubleLayerCapacity/PB.npz', Lambda2=Lambda2, a2=a2, K=K, Molarity=Molarity, y_R=y_R, z_A=z_A, z_C=z_C, phi_R=phi_R, p_R=p_R, number_cells=number_cells, relax_param=relax_param, rtol=rtol, refinement_style=refinement_style, max_iter=max_iter, return_type=return_type, Volt_start=Volt_start, Volt_end=Volt_end, n_Volts=n_Volts, Phi_Pot_Diff_dim_PB=Phi_Pot_Diff_dim_PB, Phi_Pot_Diff_dimless_PB=Phi_Pot_Diff_dimless_PB, Q_DL_dimless_PB_=Q_DL_dimless_PB_, Q_DL_dim_PB_=Q_DL_dim_PB_, C_DL_dimless_PB=C_DL_dimless_PB, C_DL_dim_PB=C_DL_dim_PB, Phi_pot_center_array_dimless_PB=Phi_pot_center_array_dimless_PB, Phi_pot_center_array_dim_PB=Phi_pot_center_array_dim_PB)
\ No newline at end of file
diff --git a/examples/ReproducableCode/DoubleLayerCapacity/Solvation.py b/examples/ReproducableCode/DoubleLayerCapacity/Solvation.py
index f47ead7067c336c833fa81aa43cef8bea321f5a7..740431d5a9220975a1f0cc7678e6993df8fa7320 100644
--- a/examples/ReproducableCode/DoubleLayerCapacity/Solvation.py
+++ b/examples/ReproducableCode/DoubleLayerCapacity/Solvation.py
@@ -3,8 +3,6 @@ Jan Habscheid
Jan.Habscheid@rwth-aachen.de
This script is used to analyze the influence of the solvation on the charge of the system and the double-layer capacity.
-
-# ! This is not correctly implemented, yet.
'''
# import the src file needed to solve the system of equations
@@ -129,11 +127,12 @@ for i in range(len(kappa_vec)):
Q_DL_dimless_ = np.array(Q_DL_dimless_)
Q_DL_dim_ = np.array(Q_DL_dim_)
-
+
+# Double Layer Capacity
C_DL_dimless_PB = C_dl(Q_DL_dimless_PB_, Phi_Pot_Diff_dimless_PB)
C_DL_dimless = [C_dl(q_dl, Phi_Pot_Diff_dimless) for q_dl in Q_DL_dimless_]
-C_DL_dim_PB = C_dl(Q_DL_dim_PB_, Phi_Pot_Diff_dim)
+C_DL_dim_PB = C_dl(Q_DL_dim_PB_, Phi_Pot_Diff_dim_PB)
C_DL_dim = [C_dl(q_dl, Phi_Pot_Diff_dim) for q_dl in Q_DL_dim_]
diff --git a/examples/Visualizations/DoubleLayerCapacity.py/VisIncompressible.py b/examples/Visualizations/DoubleLayerCapacity.py/VisIncompressible.py
index ddadc8e409114840fa7f150cdf33f2a7fe505320..1ce5786f8a7524c0c634aa2e9780ddc6cb66afdd 100644
--- a/examples/Visualizations/DoubleLayerCapacity.py/VisIncompressible.py
+++ b/examples/Visualizations/DoubleLayerCapacity.py/VisIncompressible.py
@@ -24,6 +24,17 @@ Phi_pot_center_array_dimless = data_Molarity['Phi_pot_center_array_dimless']
Phi_pot_center_array_dim = data_Molarity['Phi_pot_center_array_dim']
C_DL_dimless = data_Molarity['C_DL_dimless']
+data_PB = np.load('../../Data/DoubleLayerCapacity/PB.npz')
+Q_DL_dim_PB_ = data_PB['Q_DL_dim_PB_']
+Phi_Pot_Diff_dim_PB = data_PB['Phi_Pot_Diff_dim_PB']
+Q_DL_dimless_PB_ = data_PB['Q_DL_dimless_PB_']
+Phi_Pot_Diff_dimless_PB = data_PB['Phi_Pot_Diff_dimless_PB']
+C_DL_dim_PB = data_PB['C_DL_dim_PB']
+Phi_pot_center_array_dim_PB = data_PB['Phi_pot_center_array_dim_PB']
+Phi_pot_center_array_dimless_PB = data_PB['Phi_pot_center_array_dimless_PB']
+C_DL_dimless_PB = data_PB['C_DL_dimless_PB']
+Molarity_PB = data_PB['Molarity']
+
# Plotting
# Charge
@@ -32,6 +43,7 @@ labelsize = 30
lw = 6
legend_width = 8
colors = ['tab:blue', 'tab:orange', 'tab:green', 'tab:cyan']
+color_PB = 'tab:grey'
color_dimless = 'tab:purple'
color_dim = 'tab:red'
ax1_dimless = fig.add_subplot(2, 2, 1, label="1")
@@ -40,6 +52,7 @@ ax2_dimless = fig.add_subplot(2, 2, 2, label="1")
ax2_dim = fig.add_subplot(2, 2, 2, label="2", frame_on=False)
# Plot dimensionless data
+ax1_dimless.plot(Phi_Pot_Diff_dimless_PB, Q_DL_dimless_PB_, '--', color=color_PB, label=f'PB(M={Molarity_PB})', lw=lw, alpha=0.5)
for i, q_dl in enumerate(Q_DL_dimless_):
ax1_dimless.plot(Phi_Pot_Diff_dimless, q_dl, color=colors[i], label=f'M: {Molarity[i]}', lw=lw)
ax1_dimless.grid()
@@ -47,6 +60,7 @@ ax1_dimless.set_xlabel('$\delta \\varphi [-]$', color=color_dimless, fontsize=la
ax1_dimless.set_ylabel('$Q [-]$', color=color_dimless, fontsize=labelsize)
ax1_dimless.tick_params(axis='x', colors=color_dimless, labelsize=labelsize)
ax1_dimless.tick_params(axis='y', colors=color_dimless, labelsize=labelsize)
+ax1_dimless.set_ylim(np.min(Q_DL_dimless_)*10/9, np.max(Q_DL_dimless_)*10/9)
# Plot dimensional data
for i, q_dl in enumerate(Q_DL_dim_):
@@ -59,9 +73,11 @@ ax1_dim.xaxis.set_label_position('top')
ax1_dim.yaxis.set_label_position('right')
ax1_dim.tick_params(axis='x', colors=color_dim, labelsize=labelsize)
ax1_dim.tick_params(axis='y', colors=color_dim, labelsize=labelsize)
+ax1_dim.set_ylim(np.min(Q_DL_dim_)*10/9, np.max(Q_DL_dim_)*10/9)
# Double Layer Capacity
+ax2_dimless.plot(Phi_pot_center_array_dimless_PB, C_DL_dimless_PB, '--', color=color_PB, lw=lw, alpha=0.5)
for i, c_dl in enumerate(C_DL_dimless):
ax2_dimless.plot(Phi_pot_center_array_dimless, c_dl, color=colors[i], lw=lw)
ax2_dimless.grid()
@@ -69,6 +85,7 @@ ax2_dimless.set_xlabel('$\delta \\varphi [-]$', color=color_dimless, fontsize=la
ax2_dimless.set_ylabel('$C_{dl} [-]$', color=color_dimless, fontsize=labelsize)
ax2_dimless.tick_params(axis='x', colors=color_dimless, labelsize=labelsize)
ax2_dimless.tick_params(axis='y', colors=color_dimless, labelsize=labelsize)
+ax2_dimless.set_ylim(np.min(C_DL_dimless)*(-10/9), np.max(C_DL_dimless)*10/9)
for i, c_dl in enumerate(C_DL_dim):
ax2_dim.plot(Phi_pot_center_array_dim, c_dl, color=colors[i], lw=lw)
@@ -80,6 +97,7 @@ ax2_dim.xaxis.set_label_position('top')
ax2_dim.yaxis.set_label_position('right')
ax2_dim.tick_params(axis='x', colors=color_dim, labelsize=labelsize)
ax2_dim.tick_params(axis='y', colors=color_dim, labelsize=labelsize)
+ax2_dim.set_ylim(np.min(C_DL_dim)*(-10/9), np.max(C_DL_dim)*10/9)
lines_labels = [ax.get_legend_handles_labels() for ax in fig.axes]
lines, labels = [sum(lol, []) for lol in zip(*lines_labels)]
diff --git a/src/__pycache__/Eq04.cpython-312.pyc b/src/__pycache__/Eq04.cpython-312.pyc
index 7466f34eeeaac5ca4a9999d68fc19efc50dbd4e1..a66fcae846c0b47ec57c2496e41a8a825be0e98c 100644
Binary files a/src/__pycache__/Eq04.cpython-312.pyc and b/src/__pycache__/Eq04.cpython-312.pyc differ